J.6 Nitrogen oxide, NO(g)
\[\dfrac{1}{2}\mathrm{N_2}(g) + \dfrac{1}{2}\mathrm{O_2}(g) \longrightarrow \mathrm{NO}(g)\]
Data
Enthalpy reference temperature (Tr = 298.15 K); Standard state pressure = p° = 0.1 MPa
- C°p, S°, and -[G°-H°(Tr)]/T in J mol–1 K–1
- ΔH°f and ΔG°f in kJ mol–1
T (K) | C°p | S° | –[G°-H°(Tr)]/T | H° -H°(Tr) | ΔH°f | ΔG°f | log Kf |
---|---|---|---|---|---|---|---|
0 |
0 |
0 |
INFINITE |
-9.192 |
89.775 |
89.775 |
INFINITE |
100 |
32.302 |
177.031 |
237.757 |
-6.073 |
89.991 |
88.944 |
-46.46 |
200 |
30.42 |
198.747 |
213.501 |
-2.951 |
90.202 |
87.8 |
-22.931 |
250 |
30.025 |
205.488 |
211.251 |
-1.441 |
90.256 |
87.193 |
-18.218 |
298.15 |
29.845 |
210.758 |
210.758 |
0 |
90.291 |
86.6 |
-15.172 |
300 |
29.841 |
210.943 |
210.759 |
0.055 |
90.292 |
86.577 |
-15.074 |
350 |
29.823 |
215.54 |
211.122 |
1.546 |
90.316 |
85.955 |
-12.828 |
400 |
29.944 |
219.529 |
211.929 |
3.04 |
90.332 |
85.331 |
-11.143 |
450 |
30.175 |
223.068 |
212.974 |
4.542 |
90.343 |
84.705 |
-9.832 |
500 |
30.486 |
226.263 |
214.145 |
6.059 |
90.352 |
84.079 |
-8.784 |
600 |
31.238 |
231.886 |
216.646 |
9.144 |
90.366 |
82.822 |
-7.21 |
700 |
32.028 |
236.761 |
219.179 |
12.307 |
90.381 |
81.564 |
-6.086 |
800 |
32.767 |
241.087 |
221.652 |
15.548 |
90.398 |
80.303 |
-5.243 |
900 |
33.422 |
244.985 |
224.031 |
18.858 |
90.417 |
79.041 |
-4.587 |
1000 |
33.987 |
248.536 |
226.307 |
22.229 |
90.437 |
77.775 |
-4.063 |
1100 |
34.468 |
251.799 |
228.478 |
25.653 |
90.457 |
76.508 |
-3.633 |
1200 |
34.877 |
254.816 |
230.549 |
29.12 |
90.476 |
75.239 |
-3.275 |
1300 |
35.226 |
257.621 |
232.525 |
32.626 |
90.493 |
73.969 |
-2.972 |
1400 |
35.524 |
260.243 |
234.412 |
36.164 |
90.508 |
72.697 |
-2.712 |
1500 |
35.78 |
262.703 |
236.217 |
39.729 |
90.518 |
71.425 |
-2.487 |
1600 |
36.002 |
265.019 |
237.945 |
43.319 |
90.525 |
70.151 |
-2.29 |
1700 |
36.195 |
267.208 |
239.603 |
46.929 |
90.526 |
68.878 |
-2.116 |
1800 |
36.364 |
269.282 |
241.195 |
50.557 |
90.522 |
67.605 |
-1.962 |
1900 |
36.514 |
271.252 |
242.725 |
54.201 |
90.511 |
66.332 |
-1.824 |
2000 |
36.647 |
273.128 |
244.199 |
57.859 |
90.494 |
65.06 |
-1.699 |
2100 |
36.767 |
274.919 |
245.619 |
61.53 |
90.469 |
63.788 |
-1.587 |
2200 |
36.874 |
276.632 |
246.99 |
65.212 |
90.438 |
62.519 |
-1.484 |
2300 |
36.971 |
278.273 |
248.315 |
68.904 |
90.398 |
61.251 |
-1.391 |
2400 |
37.06 |
279.849 |
249.596 |
72.606 |
90.35 |
59.984 |
-1.306 |
2500 |
37.141 |
281.363 |
250.837 |
76.316 |
90.295 |
58.72 |
-1.227 |
2600 |
37.216 |
282.822 |
252.039 |
80.034 |
90.231 |
57.458 |
-1.154 |
2700 |
37.285 |
284.227 |
253.205 |
83.759 |
90.16 |
56.199 |
-1.087 |
2800 |
37.35 |
285.585 |
254.338 |
87.491 |
90.081 |
54.943 |
-1.025 |
2900 |
37.41 |
286.896 |
255.438 |
91.229 |
89.994 |
53.689 |
-0.967 |
3000 |
37.466 |
288.165 |
256.508 |
94.973 |
89.899 |
52.439 |
-0.913 |
3100 |
37.519 |
289.395 |
257.549 |
98.722 |
89.798 |
51.192 |
-0.863 |
3200 |
37.57 |
290.587 |
258.563 |
102.477 |
89.689 |
49.948 |
-0.815 |
3300 |
37.617 |
291.744 |
259.551 |
106.236 |
89.574 |
48.708 |
-0.771 |
3400 |
37.663 |
292.867 |
260.514 |
110 |
89.451 |
47.472 |
-0.729 |
3500 |
37.706 |
293.96 |
261.454 |
113.768 |
89.323 |
46.239 |
-0.69 |
3600 |
37.747 |
295.022 |
262.372 |
117.541 |
89.189 |
45.01 |
-0.653 |
3700 |
37.787 |
296.057 |
263.269 |
121.318 |
89.049 |
43.784 |
-0.618 |
3800 |
37.825 |
297.065 |
264.145 |
125.098 |
88.903 |
42.563 |
-0.585 |
3900 |
37.862 |
298.048 |
265.002 |
128.883 |
88.752 |
41.346 |
-0.554 |
4000 |
37.898 |
299.008 |
265.84 |
132.671 |
88.596 |
40.132 |
-0.524 |
4100 |
37.933 |
299.944 |
266.66 |
136.462 |
88.434 |
38.922 |
-0.496 |
4200 |
37.966 |
300.858 |
267.464 |
140.257 |
88.268 |
37.717 |
-0.469 |
4300 |
37.999 |
301.752 |
268.251 |
144.056 |
88.097 |
36.515 |
-0.444 |
4400 |
38.031 |
302.626 |
269.022 |
147.857 |
87.922 |
35.318 |
-0.419 |
4500 |
38.062 |
303.481 |
269.778 |
151.662 |
87.741 |
34.124 |
-0.396 |
4600 |
38.092 |
304.318 |
270.52 |
155.469 |
87.556 |
32.934 |
-0.374 |
4700 |
38.122 |
305.137 |
271.248 |
159.28 |
87.366 |
31.749 |
-0.353 |
4800 |
38.151 |
305.94 |
271.962 |
163.094 |
87.171 |
30.568 |
-0.333 |
4900 |
38.18 |
306.727 |
272.664 |
166.91 |
86.97 |
29.391 |
-0.313 |
5000 |
38.208 |
307.499 |
273.353 |
170.73 |
86.765 |
28.218 |
-0.295 |
5100 |
38.235 |
308.256 |
274.03 |
174.552 |
86.553 |
27.049 |
-0.277 |
5200 |
38.262 |
308.998 |
274.695 |
178.377 |
86.336 |
25.884 |
-0.26 |
5300 |
38.289 |
309.728 |
275.349 |
182.204 |
86.112 |
24.724 |
-0.244 |
5400 |
38.316 |
310.443 |
275.993 |
186.034 |
85.881 |
23.568 |
-0.228 |
5500 |
38.342 |
311.147 |
276.625 |
189.867 |
85.644 |
22.416 |
-0.213 |
5600 |
38.367 |
311.838 |
277.248 |
193.703 |
85.399 |
21.269 |
-0.198 |
5700 |
38.393 |
312.517 |
277.861 |
197.541 |
85.146 |
20.125 |
-0.184 |
5800 |
38.418 |
313.185 |
278.464 |
201.381 |
84.884 |
18.987 |
-0.171 |
5900 |
38.443 |
313.842 |
279.058 |
205.224 |
84.613 |
17.853 |
-0.158 |
6000 |
38.468 |
314.488 |
279.643 |
209.07 |
84.331 |
16.724 |
-0.146 |