J.2 Water, H2O(g)
\[\mathrm{H_2}(g) + \dfrac{1}{2}\mathrm{O_2}(g) \longrightarrow \mathrm{H_2O}(g)\]
Data
Enthalpy reference temperature (Tr = 298.15 K); Standard state pressure = p° = 0.1 MPa
- C°p, S°, and -[G°-H°(Tr)]/T in J mol–1 K–1
- ΔH°f and ΔG°f in kJ mol–1
T (K) | C°p | S° | –[G°-H°(Tr)]/T | H° -H°(Tr) | ΔH°f | ΔG°f | log Kf |
---|---|---|---|---|---|---|---|
0 |
0 |
0 |
INFINITE |
-9.904 |
-238.921 |
-238.921 |
INFINITE |
100 |
33.299 |
152.388 |
218.534 |
-6.615 |
-240.083 |
-236.584 |
123.579 |
200 |
33.349 |
175.485 |
191.896 |
-3.282 |
-240.9 |
-232.766 |
60.792 |
298.15 |
33.59 |
188.834 |
188.834 |
0 |
-241.826 |
-228.582 |
40.047 |
300 |
33.596 |
189.042 |
188.835 |
0.062 |
-241.844 |
-228.5 |
39.785 |
400 |
34.262 |
198.788 |
190.159 |
3.452 |
-242.846 |
-223.901 |
29.238 |
500 |
35.226 |
206.534 |
192.685 |
6.925 |
-243.826 |
-219.051 |
22.884 |
600 |
36.325 |
213.052 |
195.55 |
10.501 |
-244.758 |
-214.007 |
18.631 |
700 |
37.495 |
218.739 |
198.465 |
14.192 |
-245.632 |
-208.812 |
15.582 |
800 |
38.721 |
223.825 |
201.322 |
18.002 |
-246.443 |
-203.496 |
13.287 |
900 |
39.987 |
228.459 |
204.084 |
21.938 |
-247.185 |
-198.083 |
11.496 |
1000 |
41.268 |
232.738 |
206.738 |
26 |
-247.857 |
-192.59 |
10.06 |
1100 |
42.536 |
236.731 |
209.285 |
30.191 |
-248.46 |
-187.033 |
8.881 |
1200 |
43.768 |
240.485 |
211.73 |
34.506 |
-248.997 |
-181.425 |
7.897 |
1300 |
44.945 |
244.035 |
214.08 |
38.942 |
-249.473 |
-175.774 |
7.063 |
1400 |
46.054 |
247.407 |
216.341 |
43.493 |
-249.894 |
-170.089 |
6.346 |
1500 |
47.09 |
250.62 |
218.52 |
48.151 |
-250.265 |
-164.376 |
5.724 |
1600 |
48.05 |
253.69 |
220.623 |
52.908 |
-250.592 |
-158.639 |
5.179 |
1700 |
48.935 |
256.63 |
222.655 |
57.758 |
-250.881 |
-152.883 |
4.698 |
1800 |
49.749 |
259.451 |
224.621 |
62.693 |
-251.138 |
-147.111 |
4.269 |
1900 |
50.496 |
262.161 |
226.526 |
67.706 |
-251.368 |
-141.325 |
3.885 |
2000 |
51.18 |
264.769 |
228.374 |
72.79 |
-251.575 |
-135.528 |
3.54 |
2100 |
51.823 |
267.282 |
230.167 |
77.941 |
-251.762 |
-129.721 |
3.227 |
2200 |
52.408 |
269.706 |
231.909 |
83.153 |
-251.934 |
-123.905 |
2.942 |
2300 |
52.947 |
272.048 |
233.604 |
88.421 |
-252.092 |
-118.082 |
2.682 |
2400 |
53.444 |
274.312 |
235.253 |
93.741 |
-252.239 |
-112.252 |
2.443 |
2500 |
53.904 |
276.503 |
236.86 |
99.108 |
-252.379 |
-106.416 |
2.223 |
2600 |
54.329 |
278.625 |
238.425 |
104.52 |
-252.513 |
-100.575 |
2.021 |
2700 |
54.723 |
280.683 |
239.952 |
109.973 |
-252.643 |
-94.729 |
1.833 |
2800 |
55.089 |
282.68 |
241.443 |
115.464 |
-252.771 |
-88.878 |
1.658 |
2900 |
55.43 |
284.619 |
242.899 |
120.99 |
-252.897 |
-83.023 |
1.495 |
3000 |
55.748 |
286.504 |
244.321 |
126.549 |
-253.024 |
-77.163 |
1.344 |
3100 |
56.044 |
288.337 |
245.711 |
132.139 |
-253.152 |
-71.298 |
1.201 |
3200 |
56.323 |
290.12 |
247.071 |
137.757 |
-253.282 |
-65.43 |
1.068 |
3300 |
56.583 |
291.858 |
248.402 |
143.403 |
-253.416 |
-59.558 |
0.943 |
3400 |
56.828 |
293.55 |
249.705 |
149.073 |
-253.553 |
-53.681 |
0.825 |
3500 |
57.058 |
295.201 |
250.982 |
154.768 |
-253.696 |
-47.801 |
0.713 |
3600 |
57.276 |
296.812 |
252.233 |
160.485 |
-253.844 |
-41.916 |
0.608 |
3700 |
57.48 |
298.384 |
253.459 |
166.222 |
-253.997 |
-36.027 |
0.509 |
3800 |
57.675 |
299.919 |
254.661 |
171.98 |
-254.158 |
-30.133 |
0.414 |
3900 |
57.859 |
301.42 |
255.841 |
177.757 |
-254.326 |
-24.236 |
0.325 |
4000 |
58.033 |
302.887 |
256.999 |
183.552 |
-254.501 |
-18.334 |
0.239 |
4100 |
58.199 |
304.322 |
258.136 |
189.363 |
-254.684 |
-12.427 |
0.158 |
4200 |
58.357 |
305.726 |
259.252 |
195.191 |
-254.876 |
-6.516 |
0.081 |
4300 |
58.507 |
307.101 |
260.349 |
201.034 |
-255.078 |
-0.6 |
0.007 |
4400 |
58.65 |
308.448 |
261.427 |
206.892 |
-255.288 |
5.32 |
-0.063 |
4500 |
58.787 |
309.767 |
262.486 |
212.764 |
-255.508 |
11.245 |
-0.131 |
4600 |
58.918 |
311.061 |
263.528 |
218.65 |
-255.738 |
17.175 |
-0.195 |
4700 |
59.044 |
312.329 |
264.553 |
224.548 |
-255.978 |
23.111 |
-0.257 |
4800 |
59.164 |
313.574 |
265.562 |
230.458 |
-256.229 |
29.052 |
-0.316 |
4900 |
59.275 |
314.795 |
266.554 |
236.38 |
-256.491 |
34.998 |
-0.373 |
5000 |
59.39 |
315.993 |
267.531 |
242.313 |
-256.763 |
40.949 |
-0.428 |
5100 |
59.509 |
317.171 |
268.493 |
248.258 |
-257.046 |
46.906 |
-0.48 |
5200 |
59.628 |
318.327 |
269.44 |
254.215 |
-257.338 |
52.869 |
-0.531 |
5300 |
59.746 |
319.464 |
270.373 |
260.184 |
-257.639 |
58.838 |
-0.58 |
5400 |
59.864 |
320.582 |
271.293 |
266.164 |
-257.95 |
64.811 |
-0.627 |
5500 |
59.982 |
321.682 |
272.199 |
272.157 |
-258.268 |
70.791 |
-0.672 |
5600 |
60.1 |
322.764 |
273.092 |
278.161 |
-258.595 |
76.777 |
-0.716 |
5700 |
60.218 |
323.828 |
273.973 |
284.177 |
-258.93 |
82.769 |
-0.758 |
5800 |
60.335 |
324.877 |
274.841 |
290.204 |
-259.272 |
88.767 |
-0.799 |
5900 |
60.453 |
325.909 |
275.698 |
296.244 |
-259.621 |
94.77 |
-0.839 |
6000 |
60.571 |
326.926 |
276.544 |
302.295 |
-259.977 |
100.78 |
-0.877 |